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Title: The theoretical evaluation of the poly(3,4-dimetylpyrrole) cathodic electrodeposition assisted by manganate ions
Authors: Tkach, Volodymyr V
Storoshchuk, Nataliia M.
Roraaniv, Lyudmyla V.
De Oliveira, Sílvio C.
Luganska, Olga V.
Gala, Hélder Briosae
Tchikuala, Emílio Figueira
Yagodynets, Petro I.
Keywords: Conducting polymers
Cathodic electrodeposition
Manganate ions
Stable steady-state
Issue Date: 2018
Series/Report no.: Vietnam Journal of Chemistry;No 56 .- Page.440-444
Abstract: The theoretical description of poly(3,4-dimethylpyrrole) cathodic electrodeposition in alkaline media has been reported for the first time. The electrochemical deposition of conducting polymer on cathode is realized by in situ formation of manganate-ions (MnO₄²⁻) as oxidizing agents, and the proper polymer may be doped by hypomanagate, ions (MnO₄³⁻). The stable steady-state in this system was established rapidly and efficiently, and the polymer surface has to be well developed. No electrochemical instabilities, typical for anodic direct electropolymerization, was observed.
ISSN: 2525-2321
Appears in Collections:Vietnam Journal of Chemistry

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